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A mini-review on air-stable organometallic Lewis acids: synthesis, characterization, and catalytic application in organic synthesis

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成果类型:
期刊论文
作者:
Qiu, Renhua*;Chen, Yi(陈懿);Yin, Shuang-Feng;Xu, Xinhua;Au, Chak-Tong
通讯作者:
Qiu, Renhua
作者机构:
[Chen, Yi; Au, Chak-Tong; Yin, Shuang-Feng; Qiu, Renhua; Xu, Xinhua] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
[Chen, Yi] Hunan Univ Chinese Med, Coll Basic Med, Changsha 410208, Hunan, Peoples R China.
[Au, Chak-Tong] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China.
通讯机构:
[Qiu, Renhua] H
Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
语种:
英文
期刊:
RSC Advances
ISSN:
2046-2069
年:
2012
卷:
2
期:
29
页码:
10774-10793
基金类别:
NSF of Hunan Province [10JJ1003]; NSFCNational Natural Science Foundation of China (NSFC) [21003040, 20973056]; program for New Century Excellent Talents in UniversitiesProgram for New Century Excellent Talents in University (NCET) [NCET-10-0371]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities
机构署名:
本校为其他机构
院系归属:
医学院
摘要:
Organometallic Lewis acids play an important role in modern organic synthesis. How to design and synthesize highly efficient and recyclable organometallic Lewis acid catalysts that can be conveniently applied in chemical reactions are key issues for sustainable synthetic processes. In general, stronger acidity means higher catalytic activity for organometallic Lewis acids. However, with the rise in acidity, the compound becomes more susceptible to hydrolysis and cannot be recycled. Simultaneous improvement of the hygroscopic character and Lewis...

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