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Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes.

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WOS被引频次:103
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成果类型:
期刊论文
作者:
Zhang, Cheng-Pan;Wang, Zong-Ling;Chen, Qing-Yun;Zhang, Chun-Tao;Gu, Yu-Cheng;Xiao, Ji-Chang*
通讯作者:
Xiao, Ji-Chang
作者机构:
[Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Xiao, Ji-Chang] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China.
[Wang, Zong-Ling; Zhang, Chun-Tao] Hunan Univ Chinese Med, Changsha 410208, Hunan, Peoples R China.
[Gu, Yu-Cheng] Syngenta, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England.
[Xiao, Ji-Chang] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China.
通讯机构:
[Xiao, Ji-Chang] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China.
语种:
英文
期刊:
Chemical communications (Cambridge, England)
ISSN:
1359-7345
年:
2011
卷:
47
期:
23
页码:
6632-6634
文献类别:
WOS:Article
所属学科:
ESI学科类别:化学;WOS学科类别:Chemistry, Multidisciplinary
入藏号:
WOS:000291113000033;PMID:21559547
机构署名:
本校为其他机构
摘要:
The CF(3) radical was generated from the reaction of S-(trifluoromethyl)diphenylsulfonium triflate with Na(2)S(2)O(4) or HOCH(2)SO(2)Na under suitable conditions without further reduction. Based on this, a method for the synthesis of alpha-trifluoromethylated ketones has been successfully developed.
参考文献:
ALLEN AD, 1989, TETRAHEDRON LETT, V30, P1315, DOI 10.1016/S0040-4039(00)99453-X
Begue J. -P., 2008, BIOORGANIC MED CHEM
Bhadury PS, 2007, J ANAL APPL PYROL, V78, P288, DOI 10.1016/j.jaap.2006.07.006
Brace NO, 1999, J FLUORINE CHEM, V93, P1, DOI 10.1016/S0022-1139(98)00255-3
Choudhury-Mukherjee Indrani, 2003, Journal of Medicinal Chemistry, V46, P2494, DOI 10.1021/jm020546r

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