Synthesis, Structure and Applications of Hypervalent Organoantimony Compounds Having Intramolecular E→Sb (E = N, O, S) Coordinations

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成果类型：

期刊论文

作者：

Tan, Nianyuan;Chen, Yi;Yin, Shuangfeng*;Qiu, Renhua;Zhou, Yongbo;...

通讯作者：

Yin, Shuangfeng

作者机构：

[Tan, Nianyuan; Chen, Yi; Zhou, Yongbo; Qiu, Renhua; Yin, Shuangfeng; Au, C. T.] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China.

[Tan, Nianyuan] Hunan Inst Engn, Coll Chem & Chem Engn, Xiangtan 411104, Peoples R China.

[Chen, Yi] Hunan Univ Chinese Med, Sch Basic Med, Changsha 410208, Hunan, Peoples R China.

[Au, C. T.] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China.

通讯机构：

[Yin, Shuangfeng] H

Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China.

语种：

英文

关键词：

Organoantimony;Hypervalent compounds;Intramolecular coordination;Organic synthesis;Structure;Reagent;Catalyst;dimethylaminopiridine;triarylstibines;aromatic substituent;(N;N-dimethylamino)ethylferrocene.

期刊：

Current Organic Chemistry

ISSN：

1385-2728

年：

2012

卷：

期：

页码：

2462-2481

DOI：

10.2174/138527212803520083

基金类别：

Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [10JJ1003]; Science Research Foundation of Higher Universities of Hunan Province [10A092]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [20973056, 21003040]; program for New Century Excellent Talents in UniversitiesProgram for New Century Excellent Talents in University (NCET) [NCET-10-0371]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities

机构署名：

本校为其他机构

院系归属：

医学院

中医学院

摘要：

The review article covers the hypervalent organoantimony compounds that are with intramolecular N, O, S→Sb coordinations synthesized in the past 20 years. We describe their structures and the related coordination chemistry, highlighting a number of hypervalent stibines. These compounds have shown many applications in organic synthesis. They are useful reagents for reactions such as crosscoupling and arylation with organic halides, and addition with carbonyl compounds. They can be used as Lewis acid catalysts in organic synthesis. Furthermore, ...

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Synthesis, Structure and Applications of Hypervalent Organoantimony Compounds Having Intramolecular E→Sb (E = N, O, S) Coordinations

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