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Highly efficient and green esterification of carboxylic acids in deep eutectic solvents without any other additives

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成果类型:
期刊论文
作者:
Yasmin, Sumera;Sheng, Wen-Bing;Peng, Cai-Yun;Rahman, Atta-ur;Liao, Duan-Fang;...
通讯作者:
Wanga, Wei;Choudhary, M. Iqbal
作者机构:
[Wanga, Wei; Yasmin, Sumera; Sheng, Wen-Bing; Peng, Cai-Yun; Liao, Duan-Fang] Hunan Univ Chinese Med, Sch Pharm, TCM & Ethnomed Innovat & Dev Lab, Sino Pakistan TCM & Ethnomed Res Ctr, Changsha 410208, Hunan, Peoples R China.
[Rahman, Atta-ur; Wanga, Wei; Yasmin, Sumera; Choudhary, M. Iqbal] Univ Karachi, Int Ctr Chem & Biol Sci, Res Inst Chem, HEJ, Karachi 75270, Pakistan.
通讯机构:
[Wanga, Wei] H
[Choudhary, M. Iqbal] U
Hunan Univ Chinese Med, Sch Pharm, TCM & Ethnomed Innovat & Dev Lab, Sino Pakistan TCM & Ethnomed Res Ctr, Changsha 410208, Hunan, Peoples R China.
Univ Karachi, Int Ctr Chem & Biol Sci, Res Inst Chem, HEJ, Karachi 75270, Pakistan.
语种:
英文
关键词:
Carboxylic acids;catalyst-free;deep eutectic solvent;esterification
期刊:
Synthetic Communications
ISSN:
0039-7911
年:
2018
卷:
48
期:
1
页码:
68-75
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [81374062, 85673179]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2015JJ6082]; Education Department of Hunan Province [17C1192]; Hunan Science and Technology Department Funds [2014SK4037, 2014FJ1007]
机构署名:
本校为第一且通讯机构
院系归属:
药学院
摘要:
A protocol that carboxylic acids esterifies with the quaternary ammonium salt of deep eutectic solvent (DES) is presented, which opens a new access to ester using DES as alkylating agent, solvent, and catalyst. The reaction runs smoothly in DES without any other additives. Substituted cinnamic acids, aromatic acids, and aliphatic acids can be esterified in moderate to good yields. The advantages of this reaction include excellent functional ...

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