Proposal for the classification of sinomenine alkaloids.

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成果类型：

期刊论文

作者：

Chen, Na;Xie, Rui;Chen, Jia-Pei;Zhong, Ying-Li;Zhang, Xian-Wen;...

通讯作者：

Guo, Chun;Yang, Hua

作者机构：

[Xie, Rui; Chen, Na; Chen, Jia-Pei; Zhang, Xian-Wen; Zhong, Ying-Li] College of Bioscience and Biotechnology, Hunan Agricultural University, Changsha 410128, PR China

[Gui, Qing-Wen] College of Chemistry and Materials Science, Hunan Agricultural University, Changsha, 410128, PR China

[Guo, Chun] First Affiliated Hospital, Hunan University of Chinese Medicine, Changsha 410007, PR China. Electronic address: 27392668@qq.com

[Yang, Hua] College of Bioscience and Biotechnology, Hunan Agricultural University, Changsha 410128, PR China. Electronic address: yhua7710@126.com

通讯机构：

[Yang, Hua] C

[Guo, Chun] F

First Affiliated Hospital, Hunan University of Chinese Medicine, Changsha 410007, PR China. Electronic address:

College of Bioscience and Biotechnology, Hunan Agricultural University, Changsha 410128, PR China. Electronic address:

语种：

英文

关键词：

Morphinane;Salutaridine;Sinoacutine;Sinomenium acutum

期刊：

Fitoterapia

ISSN：

1971-551X

年：

2024

卷：

172

页码：

105713

DOI：

10.1016/j.fitote.2023.105713

机构署名：

本校为通讯机构

院系归属：

第一中医临床学院

摘要：

The chemical structure of sinoacutine is formed by a phenanthrene nucleus and an ethylamine bridge. Because it has a similar parent structure to morphine, it is subdivided into morphinane. At present, all reports have pointed out that the basic skeleton of morphine alkaloids is salutaridine (the isomer of sinoacutine), which is generated by the phenol coupling reaction of (R)-reticuline. This study shows that the biosynthetic precursors of sinoacutine and salutaridine are different. In this paper, the sinoacutine synthetase (SinSyn) gene was cloned from Sinomenium acutum and expressed SinSyn p...

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Proposal for the classification of sinomenine alkaloids.

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