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Selective fluorescent Hg(II) detection in aqueous solutions with a dye intermediate

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成果类型:
期刊论文
作者:
Young, Song*
通讯作者:
Young, Song
作者机构:
[Young, Song; Young, S] Hunan Univ Chinese Med, Sch Pharmaceut Sci, Changsha 410007, Peoples R China.
通讯机构:
[Young, Song] H
Hunan Univ Chinese Med, Sch Pharmaceut Sci, Changsha 410007, Peoples R China.
语种:
英文
关键词:
dye intermediate;fluorescent chemosensor;fluorescence quenching;mercury ions;MERCURY IONS;HG2+ IONS;SENSOR;CHEMOSENSOR;FLUOROIONOPHORE;SPECTROMETRY;FISH;SENSITIVITY;FLUOROPHORE;GENERATION
期刊:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
ISSN:
1386-1425
年:
2007
卷:
68
期:
3
页码:
705-709
机构署名:
本校为第一且通讯机构
院系归属:
药学院
摘要:
A dye intermediate, 1-amino-8-naphthol-3,6-disulfonic acid sodium (ANDS) was first used to selectively recognize Hg(II) in aqueous solutions with its fluorescence being strong quenched. The fluorescence quenching of ANDS was attributed to the formation of an inclusion complex between Hg(II) and ANDS by 2:1 complex ratio (K= 6.2 x 10(9)), which has been utilized as the basis of the fabrication of the Hg(II)-sensitive fluorescent chemosensor. The analytical performance characteristics of the proposed chemosensor were investigated. The sensor shows a linear response toward Hg(II) in the concentra...

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