Chinese Academy of SciencesChinese Academy of Sciences; National Natural Science FoundationNational Natural Science Foundation of China (NSFC) [20772147, 20972179]
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摘要：
S-(fluoroalkyl)diphenylsulfonium salts have been successfully synthesized from the reaction between fluoroalkylsul-finates and triflic anhydride in dichloromethane through a one-pot procedure. These S-(fluoroalkyl) diphenylsulfonium salts have been demonstrated to be effective reagents to fluoroalkylate C-nucleophilic substrates. Ionic substitution and radical or halogenophilic mechanism might be all involved in the react...
