Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes

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成果类型：

期刊论文

作者：

Zhang, Cheng-Pan;Wang, Zong-Ling;Chen, Qing-Yun;Zhang, Chun-Tao;Gu, Yu-Cheng;...

通讯作者：

Xiao, Ji-Chang

作者机构：

[Wang, Zong-Ling; Chen, Qing-Yun; Xiao, Ji-Chang; Zhang, Cheng-Pan] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China.

[Wang, Zong-Ling; Zhang, Chun-Tao] Hunan Univ Chinese Med, Changsha 410208, Hunan, Peoples R China.

[Gu, Yu-Cheng] Syngenta, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England.

[Xiao, Ji-Chang] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China.

通讯机构：

[Xiao, Ji-Chang] C

Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China.

语种：

英文

期刊：

Chemical Communications

ISSN：

1359-7345

年：

2011

卷：

期：

页码：

6632-6634

DOI：

10.1039/c1cc11765c

机构署名：

本校为其他机构

摘要：

The CF3 radical was generated from the reaction of S-(trifluoromethyl)diphenylsulfonium triflate with Na2S 2O4 or HOCH2SO2Na under suitable conditions without further reduction. Based on this, a method for the synthesis of α-trifluoromethylated ketones has been successfully developed....

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Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes

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