Structure and spectral performance of Co(II) and Co(III) complexes for DNA-binding: Synthesis, characterization and comparison

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成果类型：

期刊论文

作者：

Wang, Li-Le;Xu, Ming;Hu, Rui-Cheng;Dai, Ai-Guo;Tan, Shuang-Xiang;...

作者机构：

[Kong, Chun-Chu; Hu, Rui-Cheng; Tan, Shuang-Xiang; Chen, Yun-Rong; Wang, Li-Le] Hunan Normal Univ, Inst Translat Med, Hunan Prov Peoples Hosp, Affiliated Hosp 1, Changsha 410016, Peoples R China.

[Xu, Ming] Hunan Normal Univ, Dept Gastroenterol Med, Affiliated Hosp 1, Hunan Prov Peoples Hosp, Changsha 410016, Peoples R China.

[Dai, Ai-Guo] Hunan Univ Chinese Med, Med Sch, Dept Resp Dis, Changsha 410219, Peoples R China.

[Lei, Shen] Southeast Univ, Sch Chem & Chem Engn, Nanjing 210009, Peoples R China.

[Liu, Liang] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China.

语种：

英文

关键词：

Co(II) complex;Co(III) complex;DNA binding;single crystal

期刊：

Journal of Luminescence

ISSN：

0022-2313

年：

2021

卷：

237

页码：

118210-

DOI：

10.1016/j.jlumin.2021.118210

机构署名：

本校为其他机构

院系归属：

医学院

摘要：

There have been many literatures reporting the binding performance of transition metal complexes towards DNA, aiming at anti-cancer and anti-tumor drugs. However, most of these references focused on divalent transition metal cations, such as Co(II), Ni(II), Cu(II) and Zn(II). Only a few efforts have been devoted to high-valent transition metal cations. In this paper, we synthesized two Co(II) and Co(III) complexes, tris{2-(pyridin-2-yl) benzo[d]imidazole-1-ide}-cobalt(III) [denoted as Co(L)3] and bis{2-(pyridin-2-yl)benzo[d]imidazole-1-ide}-{2(pyridin-2-yl)-1H-benzo[d]imidazole}-cobalt(II) [de...

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Structure and spectral performance of Co(II) and Co(III) complexes for DNA-binding: Synthesis, characterization and comparison

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