This work was financially supported by the National Natural Science Foundation of China (Grant No. 21476065, 21571060, 21725602) and the Fundamental Research Funds for the Central Universities (Hunan University). C.-T. Au thanks Hunan University for an adjunct professorship.
机构署名：
本校为通讯机构
院系归属：
医学院
摘要：
An efficient metal-free method for the synthesis of organophosphorus compounds via oxidative cross dehydrogenative coupling of benzylic C(sp 3 )-H bonds in methylarenes with P(O)-OH compounds catalysed by cetyltrimethyl ammonium bromide (CTAB) is reported. Various methylarenes and P(O)-OH compounds are tolerated in the reaction with moderate to good yields. Compared to previous studies, the present study extends the substrate scope and adopts a new reaction system of an ammonium salt catalyst (CTAB) and an oxidant (DTBP). The results of control...
